Impact of Synthesis Conditions in Na-Rich Prussian Blue Analogues
نویسندگان
چکیده
Sodium-rich iron hexacyanoferrates were prepared by coprecipitation, hydrothermal route, and under reflux, with or without dehydration. They obtained different structures described in cubic, orthorhombic, rhombohedral symmetry, variable compositions sodium, water, cationic vacancies a variety of morphologies. This series sodium-rich Prussian blue analogues allowed addressing the relationship between synthesis conditions, composition, structure, morphology, electrochemical properties Na-ion batteries. A new orthorhombic phase Na1.8Fe2(CN)6·0.7H2O composition synthesized an route at 140 °C is reported for first time, whereas Na2Fe2(CN)6·2H2O previously monoclinic shows fact structure.
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ژورنال
عنوان ژورنال: ACS Applied Materials & Interfaces
سال: 2021
ISSN: ['1944-8244', '1944-8252']
DOI: https://doi.org/10.1021/acsami.1c09378